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Year : 2013, Volume : 38, Issue : 1to4
First page : ( 51) Last page : ( 56)
Print ISSN : 0379-0479. Online ISSN : 2349-2120. Published online : 2013  3.

Thermoelectric response of FexSe1/2Te1/2(x=0.95, 1.00, 1.05 and 1.10) superconductors

Sudesh1, Rani Stufi1, Okram G. S.2, Varma G. D.1

1Department of Physics, Indian Institute of Technology Roorkee, Roorkee-247667, India

2IUC-DAE C.S.R., University Campus, Khandwa Road, Indore-452001, India

Abstract

In the present work we have tried to explore the nature of charge carriers, Fermi temperature, TF, and superconducting critical temperature, Tc, through the resistance and thermoelectric power measurements of FexSe1/2Te1/2 samples. The polycrystalline samples ha ve been prepared with nominal compositions FexSe1/2 Te1/2 (x=0.95, 1.00, 1.05 and 1.10) via two step solid state reaction route. X-Ray diffraction results reveal the formation of tetragonal structure in all the samples. The measurements of resistance as a function of temperature show that all the samples are superconducting. The observed superconducting transition temperatures are 12.60 K, 13.68 K, 12.42 K and 12.07 K for x= 0.95, 1.00, 1.05 and 1.10, respectively. The temperature dependent Seebeck coefficient also confirms the superconducting transition in all the samples. From temperature dependent Seebeck coefficient measurements, we have determined the Fermi temperatures and studied the nature of charge carriers. The variation of Seebeck coefficient with temperature gives us idea about the scattering mechanism and multiband character of the samples.

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Keywords

Solid state reaction, Superconductivity, Thermoelectric power, Critical temperature.

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