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Indian Journal of Scientific Research
Year : 2018, Volume : 9, Issue : 1
First page : ( 19) Last page : ( 25)
Print ISSN : 0976-2876. Online ISSN : 2250-0138.
Article DOI : 10.5958/2250-0138.2018.00004.4

Structural and dielectric study of heavy rare-earth zirconate

Rani Priyanka, Singh S.V., Singh U.P., Yadav S.K.

Department of Physics, Tilak Dhari Post Graduate College, Jaunpur, U.P., India

Online published on 6 September, 2019.

Abstract

The synthesis, characterization and dielectric properties of R2Zr2O7, where R = Ho and Er have been studied. All the rare earth zirconate were prepared by solid state reaction technique and characterized by XRD, differential thermal analysis (DTA), thermogravimetric analysis (TGA) and derivative thermogravimetry (DTG). The XRD characterization shows the formation of single phase orthorhombic structure at room temperature. The dielectric constant (ε'), dielectric loss (ε'') and quality factor (Q) of the compounds have been measured at 1kHz in the temperature range 300 to 1125K. The dielectric constant of Ho2Zr2O7 and Er2Zr2O7 show rapid increase above 670K and 710K respectively. The dielectric loss shows similar behaviour as dielectric constant.

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Keywords

Dielectric constant, dielectric loss, XRD, DTA, TGA, DTG, Ho2Zr2O7, Er2Zr2O7.

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