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Spectrophotometric and kinetic study of histidine in aquo-organic medium Rathod S. D. Milind College of Science, Nagsenvana, Aurangabad, 431002. Online published on 17 October, 2020. Abstract The effect of ionic strength and H+ ion concentration on rate of reaction was confirmed. The varying concentrations of substrate and oxidant showed significant effect on rate of reaction. The observed values E a, ΔG and ΔH were determined as KJ mol-1 and ΔS as JK-1 mol-1 respectively. There was good agreement between the observed and calculated rate constants with respect to various effects. The catalytic effect of bromide and ferrous ion were examined in detail and a suitable mechanism has been proposed with the experimental results. Top Keywords Kinetics of oxidation, Aquo -organic medium, Activation parameters. Top | |
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